OK, since raising the issue and taking on board the helpful criticisms, I still think I am on the right track with the upside down case to eliminate the meniscus.
Back when I was breaking test tubes and collecting environmental samples the BIG thing to avoid in any of this was bias. Bias makes an experiment/survey not worth doing. The sampling must be random and the treatment identical and repeatable, otherwise bias creeps in. At least 2 issues arise:
1.
I still feel that judging the meniscus is too subjective, i.e. in the eye of the beholder, and its measurement or visual estimate is not repeatable if different operators are used. I looked at what I did and my method of inserting a projectile into the neck to seal it is also subjective, subject to my bias and not repeatable by others.
2.
Even though I considered carbon build up inside the case as a factor affecting volume, I erroneously believed that it would be the same (or similar enough) across all cases because they had been fired 3 times each using the same load
etc. Wrong again.
So I think I have solved the first issue. I found a silicon stopper that will seal the case mouth without protruding into the neck and allow the case to come to a stop on the bottom and stand vertically on the scale.
seal.jpg
The inside bottom is flat and the seal is around the body of the case. It will be fitted onto the case under water so the extra water captured around the outside of the neck will be the same for each case. I have miked all the necks in three places and they are within +/- 1/4 thou of 0.015". The stopper won't leak so more complete drying of the case will be possible without being pushed for time.
This morning I tried to mechanically remove the carbon from inside the case using a test tube brush on a drill. It was a failure and anyone who has de-coke a cylinder head will understand why. A bronze brush might work but none have bristles on the end to clean the base. I took some interior photos of the case to verify the cleanliness or otherwise.
Case base
caseinsidebase.jpg
Body
caseinsidewall.jpg
Under shoulder
caseinsideneck.jpg
To remedy this I have bought an ultrasonic cleaner online and await its arrival.
I intend to repeat the investigation using the same cases, which should now answer two questions:
Can case volume be inferred by its weight ? and
Does carbon removal/presence significantly affect case volume?
If the answer is yes for the second question then basing loads volumes derived from clean cases is illogical if you use the same load in a dirty case, because the volume will not be consistent.
If anyone can see errors in my logic please let me know.
Pete
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